Acid catalyzed cross‐linking of polyvinyl alcohol for humidifier membranes
نویسندگان
چکیده
Polyvinyl alcohol (PVA) is a hydrophilic polymer well known for good film forming properties, high water vapor permeance JW, and low nitrogen permeance. However, depending on molar mass temperature, PVA swells strongly in until complete dissolution. This behavior affects the usability of aqueous environments makes cross-linking necessary if higher structural integrity envisaged. In this work, networks are formed by thermal presence p-toluenesulfonic acid (TSA) investigated design experiments approach. Experimental parameters period tc, temperature ϑ TSA fraction wTSA. Cross-linking found to proceed via ether bond formation at all reaction conditions. Degradation promoted especially combination wTSA, tc ϑ. Thermal stability after preparation improved neutralizing residual TSA. Humidification membranes with JW 6423 ± 63.0 gas permeation units (GPU) fabricated coating polyvinyliden fluoride hollow fibers Summarizing, present study contributes clearer insight into TSA, resulting applicability as selective membrane layers transfer.
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ژورنال
عنوان ژورنال: Journal of Applied Polymer Science
سال: 2021
ISSN: ['1097-4628', '0021-8995']
DOI: https://doi.org/10.1002/app.51606